Titelangaben
Bethke, Christian ; Goller, Sebastian M. ; Du Ngoc, Uy Lan ; Kaysser, Simon Tino ; Altstädt, Volker ; Ruckdäschel, Holger:
Tailoring Epoxy Resin Foams by Pre-Curing with Neat Amine Hardeners and Its Derived Carbamates.
In: Polymers.
Bd. 13
(2021)
Heft 8
.
- 1348.
ISSN 2073-4360
DOI: https://doi.org/10.3390/polym13081348
Angaben zu Projekten
Projekttitel: |
Offizieller Projekttitel Projekt-ID Open Access Publizieren Ohne Angabe |
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Projektfinanzierung: |
Deutsche Forschungsgemeinschaft European Union Horizon 2020 research and innovation program |
Abstract
The use of amine-based carbamates with their dual function, acting as amine curing agents and CO2 blowing agents after their decomposition without by-products, are promising for ecofriendly epoxy foams as high-performance materials. However, controlling cell morphology requires a proper adjustment of the viscosity at the foaming step. The viscosity is altered not only by blending neat amine and its derived carbamate at a fixed pre-curing time, but also by changing the pre-curing time at a fixed blend ratio. Within this study, diglycidylether of bisphenol A (DGEBA) epoxy resin is mixed with different blend ratios of isophorone diamine (IPDA) and its derived carbamate (B-IPDA). The systems are characterized by DSC and rheology experiments to identify the pre-curing effects on the derived epoxy foams. Epoxy foams at a blend ratio of 30/70w IPDA/B-IPDA showed the best foam morphology and an optimum Tg compared to other blend ratios. Furthermore, it was found that both pre-curing times, 2 h and 3 h, for the 30/70w IPDA/B-IPDA system reveal a more homogeneous cell structure. The study proves that the blending of neat amine and carbamate is beneficial for the foaming performance of carbamate systems.