Renaissance for Low Shrinking Resins : all-in-one Solution by Bi-Functional Vinylcyclopropane-Amides

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Pineda Contreras, Paul ; Kuttner, Christian ; Fery, Andreas ; Stahlschmidt, Ullrich ; Jérôme, Valérie ; Freitag, Ruth ; Agarwal, Seema:
Renaissance for Low Shrinking Resins : all-in-one Solution by Bi-Functional Vinylcyclopropane-Amides.
In: Chemical Communications. Bd. 51 (2015) Heft 59 . - S. 11899-11902.
ISSN 1364-548X
DOI: https://doi.org/10.1039/C5CC03901K

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Abstract

A low volume shrinking vinylcyclopropane (VCP) monomer, showing both a high reactivity and a low viscosity, was obtained by applying a sterically hindered and isomeric spacer element, incorporating intermolecular amide hydrogen bonds. The resulting properties locate this VCP system in a pronounced range that so far no other efficient and radical polymerizable resin could enter.