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Effects of organic sulfur compounds on extraction and determination of inorganic sulfate

Titelangaben

Alewell, Christine:
Effects of organic sulfur compounds on extraction and determination of inorganic sulfate.
In: Plant and Soil. Bd. 149 (1993) . - S. 141-144.
ISSN 1573-5036
DOI: https://doi.org/10.1007/BF00010771

Abstract

The common methods for determining inorganic soil sulfate may be affected by the extraction of sulfate from organic sulfur compounds such as ester sulfates. In order to test this, various synthetic organic sulfur compounds (ranging from ester sulfates to sulfonates and C-bonded sulfur) were extracted with deionized water or with two common sulfate extractors (0.5M NaHCO 3 and 0.02M NaH2PO4). Similar amounts of dissolved sulfate were detected in all extracts of the aromatic ester sulfate hydroxyquinoline sulfate. Sulfate was not released from aliphatic ester sulfates or C-bonded sulfur. Ion chromatography was compared to a turbidimetric method for the determination of sulfate. The latter method, based on BaSO4-precipitation , appeared to be unsuitable for determining sulfate inorganically influenced solutions. Barium precipitated sulfate as well as ester sulfates. Furthermore, the photometry of BaSO4 was influenced by specific absorption of dissolved organic compounds, leading toa misinterpretation of the sulfate concentration in the solution.

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Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Zusätzliche Informationen: BAYCEER6818
Institutionen der Universität: Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Geowissenschaften > Lehrstuhl Bodenökologie
Forschungseinrichtungen > Zentrale wissenschaftliche Einrichtungen > Bayreuther Zentrum für Ökologie und Umweltforschung - BayCEER
Fakultäten
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Geowissenschaften
Forschungseinrichtungen
Forschungseinrichtungen > Zentrale wissenschaftliche Einrichtungen
Titel an der UBT entstanden: Ja
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik
Eingestellt am: 30 Okt 2015 07:19
Letzte Änderung: 28 Okt 2024 12:24
URI: https://eref.uni-bayreuth.de/id/eprint/21039