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Trace analysis of airborne haloacetates

Titelangaben

Frank, Hartmut ; Renschen, Dirk ; Klein, Armin ; Scholl, Harald:
Trace analysis of airborne haloacetates.
In: HRC : Journal of High Resolution Chromatography. Bd. 18 (1995) Heft 2 . - S. 83-88.
ISSN 0935-6304
DOI: https://doi.org/10.1002/jhrc.1240180203

Abstract

Haloacetates in various environmental compartments can be determined by gas chromatography-negative-ion chemical-ionization mass spectrometry after derivatization with l-pentafluorophenyl diazoethane. Detection limits in absolute amounts per injection are between 0.01 fg (chlorodifluoroacetate) and 80 fg (monofluoroacetate). Sampling of haloacetates in urban air was performed by means of cylindrical denuders coated with alkalized glycerol. The haloacetates detected are trifluoro-, monochloro-, dichloro-, trichloro-, monobromo-, and dibromoacetate. The concentrations in ambient air fluctuate strongly, e.g. between 20 and 3000 pg/m(3) for TFA. Haloacetates are also found in river waters and tree foliage. A major problem is interference from contamination with trifluoro- and trichloroacetate.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Zusätzliche Informationen: BAYCEER33956
Institutionen der Universität: Forschungseinrichtungen > Forschungszentren > Bayreuther Zentrum für Ökologie und Umweltforschung - BayCEER
Forschungseinrichtungen
Forschungseinrichtungen > Forschungszentren
Titel an der UBT entstanden: Ja
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik
Eingestellt am: 12 Feb 2016 07:15
Letzte Änderung: 12 Feb 2016 07:15
URI: https://eref.uni-bayreuth.de/id/eprint/30661