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Trace analysis of airborne haloacetates

Title data

Frank, Hartmut ; Renschen, Dirk ; Klein, Armin ; Scholl, Harald:
Trace analysis of airborne haloacetates.
In: HRC : Journal of High Resolution Chromatography. Vol. 18 (1995) Issue 2 . - pp. 83-88.
ISSN 0935-6304
DOI: https://doi.org/10.1002/jhrc.1240180203

Abstract in another language

Haloacetates in various environmental compartments can be determined by gas chromatography-negative-ion chemical-ionization mass spectrometry after derivatization with l-pentafluorophenyl diazoethane. Detection limits in absolute amounts per injection are between 0.01 fg (chlorodifluoroacetate) and 80 fg (monofluoroacetate). Sampling of haloacetates in urban air was performed by means of cylindrical denuders coated with alkalized glycerol. The haloacetates detected are trifluoro-, monochloro-, dichloro-, trichloro-, monobromo-, and dibromoacetate. The concentrations in ambient air fluctuate strongly, e.g. between 20 and 3000 pg/m(3) for TFA. Haloacetates are also found in river waters and tree foliage. A major problem is interference from contamination with trifluoro- and trichloroacetate.

Further data

Item Type: Article in a journal
Refereed: Yes
Additional notes: BAYCEER33956
Institutions of the University: Research Institutions > Research Centres > Bayreuth Center of Ecology and Environmental Research- BayCEER
Research Institutions
Research Institutions > Research Centres
Result of work at the UBT: Yes
DDC Subjects: 500 Science
Date Deposited: 12 Feb 2016 07:15
Last Modified: 12 Feb 2016 07:15
URI: https://eref.uni-bayreuth.de/id/eprint/30661