Synthesis and structural analysis of CaFe₂O₄-type single crystals in the NaAlSiO₄-MgAl₂O₄-Fe₃O₄ system

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Ishii, Takayuki ; Criniti, Giacomo ; Wang, Xiaoyu ; Glazyrin, Konstantin ; Boffa Ballaran, Tiziana:
Synthesis and structural analysis of CaFe₂O₄-type single crystals in the NaAlSiO₄-MgAl₂O₄-Fe₃O₄ system.
In: American Mineralogist. Bd. 108 (2023) Heft 1 . - S. 217-221.
ISSN 1945-3027
DOI: https://doi.org/10.2138/am-2022-8748

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Abstract

Orthorhombic CaFe2O4-structured (Cf) Na-rich aluminous silicate (space group Pbnm) is a major mineral of metabasaltic rocks at lower mantle conditions and can, therefore, significantly affect the physical properties of subducted oceanic crusts. We attempted to synthesize single crystals of Cf-type phases in the systems NaAlSiO4, NaAlSiO4-MgAl2O4, NaAlSiO4-MgAl2O4-Fe3O4, and NaAlSiO4-MgAl2O4-Fe3O4-H2O at 23–26 GPa and 1100–2200 °C. Under dry conditions, single crystals of Cf-type phase up to 100–150 μm in size were recovered from 23 GPa and 2000–2200 °C. Single-crystal X-ray diffraction and composition analyses suggest that the synthesized Cf-type phases have a few percent of vacancies in the eightfold-coordinated site with Na, Mg, and Fe2+ and partially disordered Al and Si in the octahedral sites. Iron-bearing Cf-type phases have 32–34% Fe3+ that is hosted both in the octahedral sites and in the eightfold-coordinated site. In NaAlSiO4-MgAl2O4-Fe3O4-H2O system, no formation of Cf-type phase was observed at 24 GPa and 1100–2000 °C due to the formation of hydrous Na-rich melt and Al-rich oxides or hydroxides, suggesting the possible absence of Cf-type phase in the hydrous basaltic crust. The single-crystal syntheses of Cf-type phases will be useful for investigating their physical properties, potentially improving models of lower mantle structure and dynamics.