Flexible, Heat-Resistant, and Flame-Retardant Glass Fiber Nonwoven/Glass Platelet Composite Separator for Lithium-Ion Batteries

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Schadeck, Ulrich ; Kyrgyzbaev, Kanat ; Zettl, Heiko ; Gerdes, Thorsten ; Moos, Ralf:
Flexible, Heat-Resistant, and Flame-Retardant Glass Fiber Nonwoven/Glass Platelet Composite Separator for Lithium-Ion Batteries.
In: Energies. Bd. 11 (2018) Heft 4 . - 999.
ISSN 1996-1073
DOI: https://doi.org/10.3390/en11040999

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Abstract

A new type of high-temperature stable and self-supporting composite separator for lithium-ion batteries was developed consisting of custom-made ultrathin micrometer-sized glass platelets embedded in a glass fiber nonwoven together with a water-based sodium alginate binder. The physical and electrochemical properties were investigated and compared to commercial polymer-based separators. Full-cell configuration cycling tests at different current rates were performed using graphite and lithium iron phosphate as electrode materials. The glass separator was high-temperature tested and showed a stability up to at least 600 °C without significant shrinking. Furthermore, it showed an exceptional wettability for non-aqueous electrolytes. The electrochemical performance was excellent compared to commercially available polymer-based separators. The results clearly show that glass platelets integrated into a glass fiber nonwoven performs remarkably well as a separator material in lithium-ion batteries and show high-temperature stability.