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Influence of Reaction-Sintering and Calcination Conditions on Thermoelectric Properties of Sm-doped Calcium Manganate CaMnO3

Titelangaben

Bresch, Sophie ; Mieller, Bjoern ; Delorme, Fabian ; Chen, Cong ; Bektas, Murat ; Moos, Ralf ; Rabe, Torsten:
Influence of Reaction-Sintering and Calcination Conditions on Thermoelectric Properties of Sm-doped Calcium Manganate CaMnO3.
In: Journal of Ceramic Science and Technology. Bd. 9 (2018) Heft 3 . - S. 289-300.
ISSN 2190-9385
DOI: https://doi.org/10.4416/JCST2018-00017

Volltext

Link zum Volltext (externe URL): Volltext

Abstract

A wide range of solid-state synthesis routes for calcium manganate is reported in the literature, but there is no systematic study about the influence of the solid-state synthesis conditions on thermoelectric properties. Therefore, this study examined the influence of calcination temperature and calcination cycles on the Seebeck coefficient, electrical conductivity, and thermal conductivity. Higher calcination temperatures and repeated calcination cycles minimized the driving force for sintering of the synthesized powder, leading to smaller shrinkage and lower densities of the sintered specimens. As the electrical conductivity increased monotonously with increasing density, a higher energy input during calcination caused deterioration of electrical conductivity. Phase composition and Seebeck coefficient of sintered calcium manganate were not influenced by the calcination procedure. The highest thermoelectric properties with the highest power factors and figures of merit were obtained by means of reaction-sintering of uncalcined powder.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Institutionen der Universität: Fakultäten > Fakultät für Ingenieurwissenschaften
Fakultäten > Fakultät für Ingenieurwissenschaften > Lehrstuhl Funktionsmaterialien > Lehrstuhl Funktionsmaterialien - Univ.-Prof. Dr.-Ing. Ralf Moos
Profilfelder > Advanced Fields > Neue Materialien
Forschungseinrichtungen > Forschungszentren > Bayreuther Materialzentrum - BayMAT
Fakultäten
Fakultäten > Fakultät für Ingenieurwissenschaften > Lehrstuhl Funktionsmaterialien
Profilfelder
Profilfelder > Advanced Fields
Forschungseinrichtungen
Forschungseinrichtungen > Forschungszentren
Titel an der UBT entstanden: Ja
Themengebiete aus DDC: 600 Technik, Medizin, angewandte Wissenschaften > 620 Ingenieurwissenschaften
Eingestellt am: 08 Okt 2018 07:39
Letzte Änderung: 13 Okt 2022 06:30
URI: https://eref.uni-bayreuth.de/id/eprint/45964