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Leupold, Nico ; Seibel, Anna Lena ; Moos, Ralf ; Panzer, Fabian:
Electrical Conductivity of Halide Perovskites Follows Expectations from Classical Defect Chemistry.
In: European Journal of Inorganic Chemistry.
(2021)
Heft 28
.
- S. 2882-2889.
ISSN 1099-0682
DOI: https://doi.org/10.1002/ejic.202100381
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Offizieller Projekttitel Projekt-ID Stabile Perowskitsolarzellen durch kontrollierte Kristallisationsprozesse und durch grundlegendes Verständnis der optischen und elektrischen Eigenschaften sowie der Defektchemie MO 1060/32-1 Trockenes Filmprozessieren hybrider Perowskite mit maßgeschneiderten optoelektronischen Eigenschaften PA 3373/3-1 |
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Deutsche Forschungsgemeinschaft |
Abstract
Defect chemistry is key to understand electrical properties of many functional materials including halide perovskites. However, expectations from defect chemistry about the dependency of defect densities on the doping regime of halide perovskites have not yet been clearly confirmed experimentally. Here, we measure the electrical conductivity of the model halide perovskite Methylammonium Lead Iodide over a wide range of iodine partial pressures. We find that with iodine partial pressure the electrical conductivity changes with different slopes in a double-logarithmic representation, indicating changes of the perovskite conductivity mechanism. Considering differences in the mobilities of the various defect species, we derive expectations about the dependence of the total conductivity of the perovskite as a function of iodine partial pressure. We find iodine vacancies dominating the conductivity at low iodine partial pressures, whereas at higher partial pressures holes govern the total conductivity. We find the concentration of iodide vacancies to be ∼1018 cm−3, in good agreement with the expected values based on intrinsic ionic disorder. Finally, for the case that the intrinsic ionic disorder concentration is overestimated, we elucidate the possibility to explain the conductivity profile by impurity induced acceptor doping in the perovskite. Thus, our work will allow to develop a more fundamental understanding about the electrical properties of halide perovskites.