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SCR-Catalyst Materials for Exhaust Gas Detection

Title data

Schönauer-Kamin, Daniela ; Moos, Ralf:
SCR-Catalyst Materials for Exhaust Gas Detection.
Event: 14th International Meeting on Chemical Sensors - IMCS 2012 , 20.-23.05.2012 , Nürnberg, Germany.
(Conference item: Conference , Other Presentation type)

Official URL: Volltext

Abstract in another language

The application of SCR-catalyst materials like vanadia-doped tungsten-titania (VWT) and ironexchanged zeolites (Fe-ZSM-5) for analyte detection in exhaust gases is investigated. Three detection modes are covered by this overview: the detection of certain gas concentrations with sensing devices comprising SCR-materials, the measurement of the electrical properties of the catalyst materials itself, and the direct determination of the catalyst status during operation by microwave method (an inoperando method). In this work, an overview on the suitability of SCR materials for gas detection at high temperatures (500 – 600 °C) is given. Various sensing principles, like mixed-potential, impedimetric, or resistive sensing, are discussed with respect to NH3 and SO2 response. A promising NH3 sensor behavior was found in case of a mixed-potential sensor with a VWT catalyst layer. Additionally, an impedimetric sensor with a VWT functional layer provides a selective NH3 response with marginal NO cross interference. Initial results of an impedimetric Fe-ZSM5 sensor indicate a strong NH3 dependency but a high NOx interfering effect is observed. For SO2 detection in coal combustion processes, two promising sensor setups utilizing VWT are investigated. Furthermore, the applicability of contactless radio-frequency method for direct determination of the amount of stored ammonia in a zeolite-based catalyst is shown.

Further data

Item Type: Conference item (Other)
Refereed: Yes
Institutions of the University: Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Chair Functional Materials > Chair Functional Materials - Univ.-Prof. Dr.-Ing. Ralf Moos
Faculties > Faculty of Engineering Science > Chair Functional Materials
Profile Fields > Advanced Fields > Advanced Materials
Research Institutions > Research Centres > Bayreuth Center for Material Science and Engineering - BayMAT
Profile Fields
Profile Fields > Advanced Fields
Research Institutions
Research Institutions > Research Centres
Result of work at the UBT: Yes
DDC Subjects: 600 Technology, medicine, applied sciences > 620 Engineering
Date Deposited: 15 Apr 2015 12:16
Last Modified: 14 Apr 2016 06:39