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An Enhanced Three-Step Oxidation Process to Improve Oxide Adhesion on Zirconium Alloys

Title data

Reif, Michael ; Scherm, Florian ; Galetz, Mathias ; Glatzel, Uwe:
An Enhanced Three-Step Oxidation Process to Improve Oxide Adhesion on Zirconium Alloys.
In: Oxidation of Metals. Vol. 82 (2014) . - pp. 99-112.
ISSN 1573-4889
DOI: https://doi.org/10.1007/s11085-014-9479-2

Abstract in another language

Oxidation of zirconium-based alloys results in a thermally-grown oxide
scale with excellent corrosion resistance, and good wear and friction properties,
which make them interesting for tribological applications. Nevertheless, adhesion of
the oxide layer to the substrate must be enhanced. A new three-step oxidation
process was introduced in order to achieve an improvement. Following an initial
oxidation step (1st step), a heat treatment was carried out in vacuum during which
the oxide dissolves and diffuses into the metallic zirconium substrate (2nd step).
These two steps resulted in an oxygen dissolution layer with increased hardness
formed in-between the oxide and the substrate, which serves as a bonding layer with
increased thickness. In a 3rd step a new oxide layer was obtained. The improved
oxide layer adhesion was characterized by indentation tests on three different groups
of oxidized samples of the newly developed alloy.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: Oxidation; Zirconium; Deoxidation; Adhesion; Oxygen diffusion
Institutions of the University: Faculties > Faculty of Engineering Science > Chair Metals and Alloys
Faculties > Faculty of Engineering Science > Chair Metals and Alloys > Chair Metals and Alloys - Univ.-Prof. Dr.-Ing. Uwe Glatzel
Profile Fields > Advanced Fields > Advanced Materials
Research Institutions > Research Centres > Bayreuth Center for Material Science and Engineering - BayMAT
Faculties
Faculties > Faculty of Engineering Science
Profile Fields
Profile Fields > Advanced Fields
Research Institutions
Research Institutions > Research Centres
Result of work at the UBT: Yes
DDC Subjects: 600 Technology, medicine, applied sciences > 620 Engineering
Date Deposited: 26 Nov 2014 13:19
Last Modified: 15 Feb 2023 10:40
URI: https://eref.uni-bayreuth.de/id/eprint/4085