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Surface hardening of TiZrNbHfTa high entropy alloy via oxidation

Title data

Dickes, Daniel ; Öztürk, Beyza ; Baier, Felix ; Berger, Pascal ; George, Easo P. ; Völkl, Rainer ; Galetz, Mathias C. ; Glatzel, Uwe:
Surface hardening of TiZrNbHfTa high entropy alloy via oxidation.
In: Corrosion Science. Vol. 217 (2023) . - 111159.
ISSN 0010-938X
DOI: https://doi.org/10.1016/j.corsci.2023.111159

Abstract in another language

We investigate the oxidation of TiZrNbHfTa high entropy alloy between 550 °C and 650 °C as a surface hardening method. Coarse-grained specimens with grain boundaries perpendicular to the surface exhibit catastrophic oxidation, while ultrafine-grained, cold-rolled specimens show a continuous mass gain and the formation of an adherent, µm-sized, vitreous oxide layer. Underneath, TiZrNbHfTa decomposes into a bcc- and an hcp-phase, while selective internal oxidation of hafnium and zirconium occurs upon oxygen inward diffusion. Oxygen concentration- and microhardness-depth profiles confirm an increase in oxygen concentration and hardness at the surface, raising the initial hardness by four times to 1522 ± 64 HV0.5.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Engineering Science > Chair Metals and Alloys > Chair Metals and Alloys - Univ.-Prof. Dr.-Ing. Uwe Glatzel
Profile Fields > Advanced Fields
Profile Fields > Advanced Fields > Advanced Materials
Research Institutions
Research Institutions > Central research institutes
Research Institutions > Central research institutes > Bayreuth Center for Material Science and Engineering - BayMAT
Result of work at the UBT: Yes
DDC Subjects: 000 Computer Science, information, general works
600 Technology, medicine, applied sciences
600 Technology, medicine, applied sciences > 620 Engineering
Date Deposited: 06 Sep 2023 06:20
Last Modified: 06 Sep 2023 06:20
URI: https://eref.uni-bayreuth.de/id/eprint/86777