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Improved tribological behavior of Ti-6Al-4V through a novel zirconium diffusion coating

Title data

Öztürk, Beyza ; White, Emma ; Dickes, Daniel ; Glatzel, Uwe ; Mengis, Lukas ; Galetz, Mathias:
Improved tribological behavior of Ti-6Al-4V through a novel zirconium diffusion coating.
In: Surface and Coatings Technology. Vol. 487 (2024) . - 130993.
ISSN 1879-3347
DOI: https://doi.org/10.1016/j.surfcoat.2024.130993

Abstract in another language

Titanium alloys, especially Ti-6Al-4V, are widely applied in the aerospace, automotive, marine, medical, and chemical industries due to their high strength, low density, good corrosion resistance, and high-temperature performance. However, the low wear resistance of Ti-6Al-4V hinders its broader applications. In this study, the influence of five different surface modifications on the tribological behavior of Ti-6Al-4V is compared. The five surface modifications were categorized as: 1) single-step process (oxidation), 2) two-step process (oxidation+reduction), 3) three-step process (oxidation+reduction+reoxidation), 4) oxidation at reduced oxygen partial pressure, and 5) a newly developed Zr slurry diffusion coating followed by subsequent oxidation to form ZrO2-enriched TiO2 on the surface. The wear tests were performed using a Si3N4 ball counterpart with a load of 5 N at a sliding velocity of 5.25 · 10−2 m/s and with a total sliding distance of 300 m. The wear mechanism for the unmodified Ti-6Al-4V was predicted and observed to be the detachment of Si3N4 particles from the counterpart and metallic particles from the substrate, subsequent oxidation of these particles via tribochemical reactions, and the adherence of the oxidized wear debris into the substrate and counterpart surface grooves. Deep ploughing grooves were not evident in the wear tracks of any surface-modified Ti-6Al-4V materials. Instead, wear debris containing Si-rich oxides formed as a tribolayer, except for the two-step processed sample. All surface treatments led to narrower and shallower wear tracks and there was no measurable material removal for the Zr diffusion-coated sample under the investigated conditions.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: Alloy; Oxidation; Slurry diffusion coating; Sliding wear; Contact mechanics
Institutions of the University: Faculties > Faculty of Engineering Science > Chair Metals and Alloys > Chair Metals and Alloys - Univ.-Prof. Dr.-Ing. Uwe Glatzel
Profile Fields > Advanced Fields
Profile Fields > Advanced Fields > Advanced Materials
Research Institutions
Research Institutions > Central research institutes
Research Institutions > Central research institutes > Bayreuth Center for Material Science and Engineering - BayMAT
Result of work at the UBT: Yes
DDC Subjects: 000 Computer Science, information, general works
600 Technology, medicine, applied sciences
600 Technology, medicine, applied sciences > 620 Engineering
Date Deposited: 19 Aug 2024 06:58
Last Modified: 19 Aug 2024 06:58
URI: https://eref.uni-bayreuth.de/id/eprint/90217