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Husain, Mohd Amir ; Besold, Johannes ; Gustafsson, Jon Petter ; Scheinost, Andreas C. ; Planer-Friedrich, Britta ; Biswas, Ashis:
Thioarsenate sorbs to natural organic matter through ferric iron-bridged ternary complexation to a lower extent than arsenite.
In: Journal of Hazardous Materials.
Bd. 482
(2025)
.
- 136531.
ISSN 0304-3894
DOI: https://doi.org/10.1016/j.jhazmat.2024.136531
Abstract
Understanding processes regulating thioarsenate (HxAsSnO4−n3−x; n = 1 – 3; x = 1 – 3) mobility is essential to predicting the fate of arsenic (As) in aquatic environments under anoxic conditions. Under such conditions, natural organic matter (NOM) is known to effectively sorb arsenite and arsenate due to metal cation-bridged ternary complexation with the NOM. However, the extent and mechanism of thioarsenate sorption onto NOM via similar complexation has not been investigated. By equilibrating monothioarsenate (representative of thioarsenate) with a peat (model NOM) with different Fe(III) loadings, this study shows that NOM can sorb monothioarsenate considerably via Fe(III)-bridging. Iron and As K-edge XAS analysis of the monothioarsenate-treated Fe-loaded peats revealed that monothioarsenate forms bidentate mononuclear edge-shared (1E) (RAs···Fe: 2.89 ± 0.02 Å) and bidentate binuclear corner-shared (2C) (RAs···Fe: 3.32 Å) complexes with organically bound Fe(O,OH)6 octahedra, in addition to direct covalent bonds with oxygen-containing functional groups (e.g., –COOH and –OH) (RAs···C: 2.74 ± 0.02 Å), upon equilibration with the Fe(III)-loaded peat. However, the extent of monothioarsenate sorption was considerably less than that of its precursor As species, arsenite, due to higher electrostatic repulsion between the negatively charged monothioarsenate and peat. This study implies that thioarsenate formation under anoxic conditions would increase As mobility by decreasing its sorption onto the NOM.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Geowissenschaften Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Geowissenschaften > Professur Umweltgeochemie Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Geowissenschaften > Professur Umweltgeochemie > Professur Umweltgeochemie - Univ.-Prof. Dr. Britta Planer-Friedrich Profilfelder > Advanced Fields > Ökologie und Umweltwissenschaften |
| Titel an der UBT entstanden: | Ja |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 550 Geowissenschaften, Geologie |
| Eingestellt am: | 22 Nov 2024 09:06 |
| Letzte Änderung: | 22 Nov 2024 09:06 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/91227 |